Transforming from a fossil-based to a bio-based economy, we need alternative solutions for both fuels and biobased chemicals and materials. Lignin is a promising bio-based compound produced as a side stream in biorefineries. It has the potential to replace fossil-based chemicals and materials in resins and energy storage applications.
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- The SmartRecovery project, funded by Business Finland, aimed to transition Finnish industries towards bio-based solutions by facilitating the commercialisation of lignin and introducing new lignin-based products to the market.
- LigniSmart technology developed at VTT allows the isolation of kraft lignin in a form suitable for diverse applications, offering an environmentally friendly process with less chemical waste than current methods.
- The lignin obtained through the new technology is beneficial for energy storage as it remains stable in its powder form during carbonisation, eliminating the need for energy-intensive grinding, and shows promise in Li-ion battery applications.
- To improve industrial quality control, chemometric methods were developed to quickly assess lignin purity and properties via FTIR spectrum without laborious traditional analytics. The research also contributed to lignin characterisation methods.
This summary is written by AI and checked by a human.
The goal of the SmartRecovery project funded by Business Finland was to promote the transition of Finnish industrial sectors to bio-based solutions by accelerating the commercialisation of lignin and enabling the market entry of new lignin-based products and materials.
Currently, the commercially available lignin is challenging to utilize in various applications in its raw form, as it requires modification. For example, lignin can be chemically modified or transformed into nanoparticles to be better suited to applications. These are good options, but they also increase costs.
The LigniSmart recovery technology developed at VTT allows isolation of kraft lignin in a form that can be utilised in different applications. Lifecycle assessment indicates that the process produces less chemical waste than the current lignin precipitation methods, thus making the new method more environmentally friendly.
"The companies involved in the project have played a significant role in the research work. We have received valuable feedback and development suggestions from them throughout the project. The main raw materials used in the project were also provided by the industrial partners," says Research Scientist and Project Manager Miriam Kellock from VTT.
Lignin isolated using the LigniSmart technology is particularly suitable for carbonisation and as hard carbon in energy storage applications
The lignin developed in the project behaves uniquely at high temperatures. Lignin recovered using the developed technology is stable and, unlike commercial lignin, it does not foam during carbonisation. As a result, the lignin remains in powder form even after heating. This is a significant advantage in the further processing of hard carbon, as it eliminates the laborious and energy-intensive grinding phase.
"Initial results show that the novel hard carbon performs as well as commercial hard carbon in Li-ion battery applications. The results are very promising for various energy storage applications," says Research Manager Katariina Torvinen.
Faster quality control for industrial conditions
During the project, lignin analytics were also developed with organosolv lignin. Traditional lignin analytics are labour-intensive and time-consuming. To ensure a consistent lignin product, techniques to quickly and easily evaluate the quality of lignin are needed.
"We utilised chemometrics to create a model that can assess the purity and properties of lignin directly from an FTIR spectrum, without the labour-intensive lignin analytics. The method is expected to be suitable for lignin quality control in industrial conditions," explains Kellock.
Fundamental knowledge was also gained about the internal structure of lignin particles in both laboratory and industrial conditions.
"The SmartRecovery project has allowed us to use advanced research methods, such as synchrotron radiation, to study lignin samples that are important to the industry. The results of the work support the development of lignin characterisation methods and are also interesting from the perspective of lignin interactions and precipitation behaviour," says Academy Research Fellow Paavo Penttilä from Aalto University.
The project results will be presented at a public seminar called "Lignin in focus: Key results, industry cases, and future opportunities" on 3rd of April 2025 (Innopoli2, Tekniikantie 14, Espoo).
The lignin-themed seminar is being organised by CLIC Innovation and 4R Ecosystem, the SmartRecovery project, and the ExpandFibre Transition Phase 2025.
Register online: https://link.webropolsurveys.com/EP/D419D83C38A53311
The two-year SmartRecovery to boost lignin commercialization -project was funded by Business Finland and members of the business consortium: Metsä Fibre, Fortum, Chempolis, LignEasy, Andritz, Natural Element Oy, Prosolve, and Prefere Resins.
